Characterization of acid-base properties of two gibbsite samples in the context of literature results.
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Output type: Journal article
Author list: Adekola, Fédoroff, Geckeis, Kupcik, Lefèvre, Lützenkirchen, Plaschke, Preocanin, Rabung, Schild
Publisher: Elsevier
Publication year: 2011
Journal: Journal of Colloid and Interface Science (0021-9797)
Volume number: 354
Issue number: 1
Start page: 306
End page: 17
Number of pages: -288
ISSN: 0021-9797
eISSN: 0021-9797
Languages: English-Great Britain (EN-GB)
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Open access status: closed
Abstract
Two different gibbsites, one commercial and one synthesized according to a frequently applied recipe, were studied in an interlaboratory attempt to gain insight into the origin of widely differing reports on gibbsite acid-base surface properties. In addition to a thorough characterization of the two solids, several methods relevant to the interfacial charging were applied to the two samples: potentiometric titrations to obtain the "apparent" proton related surface charge density, zeta-potential measurements characterizing the potential at the plane of shear, and Attenuated Total Reflection Infrared Spectroscopy (ATR-IR) to obtain information on the variation of counter-ion adsorption with pH (using nitrate as a probe). Values of the IEP at 9-10 and 11.2-11.3 were found for the commercial and synthesized sample, respectively. The experimental observations revealed huge differences in the charging behavior between the two samples. Such differences also appeared in the titration kinetics. A detailed literature review revealed similar disparity with no apparent systematic trend. While previously the waiting time between additions had been advocated to explain such differences among synthesized samples, our results do not support such a conclusion. Instead, we find that the amount of titrant added in each aliquot appears to have a significant influence on the titration curves. While we can relate a number of observations to others, a number of open questions and contradictions remain. We suggest various processes, which can explain the observed behavior.
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